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1 Publications

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    08/23/99 | A room-temperature molten salt prepared from AuCl3 and 1-Ethyl-3-methylimidazolium chloride.
    Schreiter ER, Stevens JE, Ortwerth MF, Freeman RG
    Inorganic Chemistry. 1999 Aug 23;38(17):3935-7. doi: 10.1021/ic990062u

    A room-temperature molten salt has been prepared from AuCl3 and 1-ethyl-3-methylimidazolium chloride (EMIC). At a ratio of 1 mol of AuCl3 to 2 mol of EMIC, the salt is a bright yellow-orange and shows Raman spectral features at 170, 328, and 352 cm-1, indicating the presence of AuCl4-. Ab initio calculations indicate that a dinuclear Au2Cl7- species containing a bridging chlorine should be stable, but no such species has been observed.

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